Ch 5. Second Law of Thermodynamics Multimedia Engineering Thermodynamics Heat Engine The SecondLaw CarnotCycle Carnot HeatEngine CarnotRefrigerator
 Chapter 1. Basics 2. Pure Substances 3. First Law 4. Energy Analysis 5. Second Law 6. Entropy 7. Exergy Analysis 8. Gas Power Cyc 9. Brayton Cycle 10. Rankine Cycle Appendix Basic Math Units Thermo Tables Search eBooks Dynamics Statics Mechanics Fluids Thermodynamics Math Author(s): Meirong Huang Kurt Gramoll ©Kurt Gramoll

 THERMODYNAMICS - THEORY Thermal Reservoirs Atmosphere, Land , and Water in a Lake are Examples of Thermal Reservoirs   Source and Sink A thermal reservoir is a specific kind of system with a large thermal energy capacity that can supply or absorb finite amounts of heat and always remains at constant temperature. Such a system can be approximated in a number of ways: Large land masses Earth's atmosphere Large bodies of water: oceans, lakes, or rivers Any physical body whose thermal energy capacity is large relative to the amount of energy it supplies or absorbs, for example, a large block of ice A reservoir that supplies energy in the form of heat is called a source and one that absorbs energy in the form of heat is called a sink. For example, atmospheric air is a source for heat pumps and a sink for air conditioners. Energy Analysis of Cycles When a system in a given initial state experiences a series of quasi-equilibrium processes and returns to its initial state, the system undergoes a cycle. The energy balance for any system undergoing a cycle takes the form       ΔEcycle = Qcycle - Wcycle where       Qcycle = the net amount of energy transferred                   by heat for the cycle,                   Qcycle = Qin- Qout       Wcycle = the net amount of energy transferred                   by work for the cycle,                   Wcycle = Wout - Win Notice that the directions of the heat and work are indicated by the subscripts in and out. Therefore, Qin, Qout, Wout, and Win are all positive numbers. Power Cycle and Refrigeration andHeat Pump Cycle Click to View Movie (72 kB) Since the system is returned to its initial state after the cycle, there is no net change in its energy. Therefore,       ΔEcycle = 0 Then the equation reduces to       Qcycle = Wcycle This expression can satisfy every thermodynamic cycle, regardless of the sequence of processes followed by the system undergoing the cycle or the nature of the substances making up the system. If the system undergoing cycles delivers a net work to its surroundings during each cycle, the cycle is called a power cycle.       Wcycle = Qin - Qout On the other hand, if the system needs work input from the surroundings to run each cycle, the cycle is called a refrigeration and heat pump cycle.       Wcycle = Qout - Qin where Wcycle has a positive value. Heat Engine What is a Heat Engine Click to View Movie (60 kB) Schematic of a Basic Power Plant Most people understand that work can always be converted to heat directly and completely. But converting heat to work requires the use of special devices. These devices are called heat engines. Heat engines operate on a cycle and receive heat from a high-temperature source, convert part of this heat to work, and then reject the remaining waste heat to a low-temperature sink during the cycle. A steam power plant is an example of heat engine. The schematic of a basic steam power plant is shown on the left. The cycle is: Heat (Qin) is transferred to the steam in the boiler from a furnace, which is the energy source. The turbine produces work (Wout ) when steam passes through it. A condenser transfers the waste heat (Qout) from steam to the energy sink, such as the atmosphere. A pump is used to carry the water from the condenser back to the boiler. Work (Win) is required to compress water to boiler pressure. The net work output from this power plant is the difference between the work output and the work input.       Wnet, out = Wout - Win From the energy balance of the cycle, the net work output is       Wnet, out = Qin - Qout Thermal Efficiency Thermal Efficiency of Heat Engine Click to View Movie(48 kB) A heat engine can only convert part of the energy it received from the source to work. A certain amount of heat is dissipated to the sink as waste heat. The fraction of the heat input that is converted to net work output is a measure of the performance of a heat engine and is called the thermal efficiency(ηth). In general, the efficiency (or performance) can be expressed in terms of the desired output and the required input as       Performance = Desired output/ Required input For heat engines, the desired output is the net work output (Wnet, out) and the required input is the heat input( Qin). Hence the thermal efficiency of a heat engine can be expressed as       Thermal efficiency = Net work output/Heat input or       ηth= Wnet, out/Qin Since Wnet, out = Qin - Qout , it can be rewritten as       ηth= (Qin- Qout)/Qin = 1 - Qout/Qin To bring uniformity to the treatment of heat engines, refrigerators, and heat pumps (wIll be introduced in the following paragraph), QH and QL are defined as QH equals the amount of heat transferred between the device (heat engines, refrigerators, and heat pumps) and a thermal reservoir of high temperature TH . QL equals the amount of heat transferred between the device (heat engines, refrigerators, and heat pumps) and a thermal reservoir of low temperature TL. Note that QH and QL are all positive numbers. Hence, the thermal efficiency for any heat engine is:       ηth= Wnet, out/QH = (QH- QL)/QH = 1 - QL/QH Note that for heat engine, QL is always less than QH ,and ηth is always less than 1. Coefficient of Performance of Refrigerators Click to View Movie (48 kB) For refrigerators or heat pumps, the efficiency is in terms of the coefficient of performance (COP). A subscript R is used to denote refrigerators (COPR) and HP for heat pumps (COPHP). A refrigerator is used to remove heat (QL) from a lower temperature space with an electric work input (Wnet,in), then dissipates the total energy from the heat input and the electric work (QH) to a higher temperature thermal reservoir. Hence, the desired output is QL and the required input is Wnet, in. So the COPR can be expressed as       COPR = Heat removed /Net work input                 = QL / Wnet, in                 = QL /( QH- QL)                 = 1/(QH/QL-1) Coefficient of Performance of Heat Pumps Click to View Movie (52 kB) A heat pump is a device which transfers heat from a low-temperature medium to a high-temperature one. For example, a heat pump is used to heat a room in winter, which transfer heat from the low-temperature outdoor air to the high-temperature air inside the room. Hence, the desired output is the heat transferred to the room (QH). Also, a net work input (Wnet, in) is necessary. The COPHP can be expressed as       COPR = Heat delivered/Required work input                 = QH / Wnet, in                 = QH /( QH- QL)                 = 1/(1-QL/QH)